Comparing the freezing process and the spin-glass phenomenon of the nanopolarization based on the MnO additives PFW-PT relaxors

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題名:	Comparing the freezing process and the spin-glass phenomenon of the nanopolarization based on the MnO additives PFW-PT relaxors
作者:	Hong,Cheng-Shong Chu, Sheng-Yuan Tsai, Cheng-Che Su, Wen-Chang Changchiene, Shih-Kuen 蔡震哲 (東方技術學院電子與資訊系)
貢獻者:	東方技術學院電子與資訊系
關鍵詞:	The ferroelectric relxor Mno The spin-glass model The modified-Landau theory
日期:	2009-07
上傳時間:	2012-12-24 15:21:39 (UTC+8)
摘要:	In this paper, pure and MnO added (1 − x)Pb(Fe2/3W1/3)O3–xPbTiO3 [(1 − x)PFW–xPT] ceramics are synthesized by using the conventional solid state oxide reaction method. The temperature dependence of the freezingprocesses is investigated by using the modified-Landau theory. This result is compared with the spin-glassphenomenon. According to the experimental data and the fitting results, the temperature-dependent local order parameters are derived from the modified-Landau theory and the spin-glass model with the experimental data separately and show similar tendencies. Furthermore, the derived local order parameters by using these two models show higher thermal stability by doping MnOadditives and decreasing PbTiO3 contents. In conclusion, the ordering degree of B-site cations is enhanced by increasing PbTiO3 compositions and is reduced by doping MnOadditives. This result is the main mechanism that induces the changes of the temperature-dependent local ordering parameters.
關聯:	Journal of Alloys and Compounds, Vol. 481 no.1-2, pp.70-74
顯示於類別:	[電子與資訊系(遊戲動畫系、動畫科)] 期刊論文

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