TUNG FANG Institutional Repository:Item 987654321/1130
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    题名: Imperfect Oriented Attachment: Accretlon and Defect Generatlon of Hexagonal lnorganic-Surfactant Nanoparticles
    作者: 范樂陽;Fahn, Y.Y.;沈傅彥;Shen, P;蘇安仲;Su, A.C.;(東方工商專科學校化學工程科)
    贡献者: 東方工商專科學校化學工程科
    日期: 2001-06-13
    上传时间: 2011-03-14 16:54:19 (UTC+8)
    摘要: Imperfect oriented attachment of nanoparticles over specific surfaces is rationalized to cause accretion and defects for the hexagonal inorganic-surfactant mesophase. Analytical electron microscopy indicates that silicate MCM-41 particles, prepared in alkaline hydrothermal condition and then surfactant (cetyltrimethylammonium bromide) leached, have well-developed {10} surfaces with monolayer steps and a rather uniform base with constant tubular wall thickness. These surfaces are beneficial to {10} vicinal and head-on attachment, causing respectively edge dislocation and twist boundary for hexagonal silicatropic liquid crystal. Brownian motion may proceed above a critical temperature for anchorage release at the interface of imperfectly attached particles until an epitaxial relationship is reached.
    關聯: NANO LETTERS, Vol.1 no.6, pp.299-303
    显示于类别:[化工與材料工程系] 期刊論文

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